Crystal Structure of 6.ALPHA.,7.ALPHA.:24.ALPHA.,25.ALPHA.-Diepoxy-5.ALPHA.,12.ALPHA.-dihydroxy-1-oxo-20S,22R-witha-2-enolide Isolated from Datura quercifolia Leaves

Five withanolides from the leaves of Datura metel L. and their inhibitory effects on nitric oxide production.

Four new withanolides named dmetelins A-D (compounds 1-4), along with the known compound 7α,27-dihydroxy-1-oxo-witha-2,5,24-trienolide (5) were isolated from the leaves of Datura metel L. (Solanaceae). Their structures were elucidated on the basis of detailed analysis of 1D and 2D NMR and mass spectrometry data. All the compounds were evaluated for their inhibitory effects on lipopolysaccharide...

Cytology of the Ferox-Quercifolia-Stramonium Triangle in Datura.

Crystal structure of 5,7-dihydroxy-3-methylcoumarin.

coumarin derivatives are of great interest in view of their sensitizing abilities in photodynamic effects and their wide occurrence in the plant kingdom. Umbelliferone, 7hydroxycoumarin, which has been known as a strongly fluorescing compound, also exhibits chemiluminescence.1 On the other hand, 7-hydroxy-4-methyl coumarin2 (Fig. 1-(I))has been applied in laser gain studies. The title compound ...

Crystal structure of 7,8-dihydroxy-4-methylcoumarin.

The structure of 7,8-dihydroxy-4-methylcoumarin was determined by an X-ray diffraction method. The compound crystallized in the triclinic space group P1, Z = 2, with a = 7.631(2), b = 9.456(5), c = 7.075(3)A, alpha = 103.13(3), beta = 91.84(3), gamma= 68.21(3) degrees, and V= 460.9(3)A3. The X-ray crystal structure was also compared with those of 5,7-dihydroxy-4-methylcoumarin and 7-hydroxy-4-m...

Crystal structure of (2E)-N-methyl-2-(2-oxo-1,2-di­hydroacenaphthylen-1-ylidene)hydrazinecarbo­thioamide

In the title compound, C14H11N3OS, the ace-naphthyl-ene ring system and hydrazinecarbo-thio-amide unit (=N-NH-C=S-NH-) are essentially coplanar [with maximum deviations from their mean planes of -0.009 (2) and 0.033 (2) Å, respectively], and make a dihedral angle of 1.59 (9)°. The mol-ecular conformation is stabilized by two weak intra-molecular hydrogen bonds (N-H⋯O and N-H⋯N), which generate ...